NYSAPPS 2016
 

For NYSS APS information, contact:
Bruce White
bwhite@binghamton.edu

Chalcogenide Perovskites for Photovoltaics

Shengbai Zhang

Department of Physics, Applied Physics and Astronomy,
Rensselaer Polytechnic Institute, Troy, New York, 12180, USA

Halide perovskites have recently emerged as a star in low-cost photovoltaics, but their low stability and the toxicity of Pb pose serious concerns. Chalcogenide perovskites ABX3 (where A and B represent 2+ and 4+ cations, respectively, and X represents either S or Se) are, on the other hand, friendlier to environment and more stable, and hence could be a good alternative to the halides. According to first-principles calculations [1], CaZrSe3 has a direct band gap of 1.35 eV, which is ideal for solar cells. Moreover, chalcogenides, like halides, have superior optical absorption properties compared to other well-known and mature solar-cell materials. Our experimental partners have experimentally synthesized several chalcongenide perovskites and made optical measurements [2], which validates the theory. In particular, the combined optical absorption and PL measurements suggest that BaZrS3 is a direct gap material with a band gap of about 1.7 eV that can be continuously tuned to 2.9 eV by forming oxychalcogenides. Other recent experimental studies of the chalcongenide perovskites also confirm our predictions [3,4]. Mixing organic-inorganic hybrid perovskites by a split-anion approach (to group-VI + group-VII elements) is another alternative to halide perovskites. We show [5] that such a splitting may offer an unusual combination between indirect band gap for long carrier lifetime and high optical absorption for efficient solar harvesting, which could be superb for photovoltaics.

[1] Y. Y. Sun, et al., Nano Lett. 15, 581 (2015).
[2] S. Pereraa, et al., Nano Energy 22, 129 (2016).
[3] W. Meng, et al., Chem. Mater., 28, 821 (2016).
[4] S. Niu, et al., Adv. Mater. 29, 1604733 (2017).
[5] Y.-Y. Sun, et al., Nanoscale 8, 6284 (2016).


For program, contact one of the organizers: For local information, contact:
Dr. Hao Zeng – haozeng@buffalo.edu
Dr. Peihong Zhang – pzhang3@buffalo.edu
Dr. Uttam Singisetti - uttamsin@buffalo.edu
Ms. Tracy Gasinsky - tracygas@buffalo.edu
Phone: 716-645-3629
Department of Physics, Buffalo, NY